Objectives Chapter 23 Amines Brown, Foote & Iverson 4th ed.
Read Chapter 23 and study the Key reactions 1, 2, 3, 4, 5, 11, 12, 13, 14, 15, &16 pg. 932-934
You should be able to:
1. Classify any amine as primary secondary tertiary or a quaternary ammonium
salt.
2. Be able to name any amine having up to ten carbon atoms according to the IUPAC system of nomenclature or visa versa.
3. Given a series of amines be able to arrange them according to increasing basicities.
4. Be able to define the terms kb and pKb.
5. Given the ir spectra of an amine be able to determine if it is primary , secondary or tertiary
6. Given a mixture an amine and an amide, be able to show how they could be separated and isolated in pure form by an extraction procedure.
7. Be able to show how simple amines can be synthesized from ammonia and alkyl halides via an SN-2 type reaction.
8. Be ale to show how a primary amine can be synthesized from a nitro group or a nitrile by reduction.
9. Be able to show how a primary amine can be synthesized via reaction of phthalimide with KOH followed by reaction with an alkyl halide.
10. Be able to show the reaction of an aromatic amine with nitrous acid (HCl + NaNO2)
11. Be able to show how an aromatic diazonium salt can be converted into an aromatic fluoride, chloride, bromide, iodide, nitrile, alcohol, or aromatic compound. (Sandmeyer reaction)
12. Be able to show how an azo dye can be formed for the reaction of an aromatic diazonium compound with a aromatic amine or phenol.
13. Show how the following molecule can be made starting with an aromatic amine:
14. Be able to do the following problems at the end of chapter 23: 16, 17, 18, 19, 20 24, 25, 27, 30, 31, 32, 34, 45